3-(Biphenyl-4-yl)-1-(4-fluorophenyl)prop-2-en-1-one

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3-(4-Biphenyl-1-yl)-3-hydr­oxy-1-phenyl­prop-2-en-1-one

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In the title compound, C(21)H(15)BrO, there are two planar rings connected through a conjugated double bond. As it crystallizes in a non-centrosymmetric space group it can be regarded as a good candidate for non-linear optical applications. The mol-ecule adopts an E configuration and the C-C=C-C torsion angle is 177.1 (4)°. The overall conformation of the compound may be described by the values...

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The crystal structure of the title compound, C(25)H(18)ClNO, shows that the mol-ecules are isolated and not involved in inter-molecular C-H⋯O or C-H⋯Cl inter-actions. However, the phenyl and quinoline rings are involved in π-π inter-actions [centroid-centroid distance = 3.8829 (9) Å].

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(E)-3-(4-Meth­oxy­phen­yl)-1-[4-(piperidin-1-yl)phen­yl]prop-2-en-1-one

The piperidine ring in the title compound, C(21)H(23)NO(2), is in a slightly distorted chair conformation. The dihedral angle between the two benzene rings is 5.6 (4)°. The dihedral angles between the propenone unit and the benzene and meth-oxy-substituted benzene rings are 5.6 (7) and 10.7 (8)°, respectively. Weak inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions contribute to ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2007

ISSN: 1600-5368

DOI: 10.1107/s1600536807023434